I was always under the impression that having a second card as a physx card actually decreases performance. Think about it, you now have thousands of extra polygons flying round the screen, more textures, more draw calls. I think adding a second card improves the experience of the game, but doesn't improve performance, in fact it does the opposite.
That's what I thought anyway...will see if ii can find some evidence to back me up. Or alternatively if anyone has something to the contrary I would be interested too