RAID 0

Go into your bios, turn on RAID for those two drives. Save that, and allow it to reboot, at the point where the raid controller boots, press the buttons it says you press (ctrl A or something). Once you've done that, configure the two disks as RAID 0, then install windows. If you already have an install, it will ot be easy (in most cases impossible) to get that install on the new drive as the RAID drivers won't be loaded.
 
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