Well, I received more fluid this morning which surprised me, as I was not expecting to get it until Monday. So a big thank you to SpecialTech! I filled the loop and got it running, and have managed to get practically all of the air out of the loop.
Then came the moment of truth, turning the system on. As this was my first build I have been very careful about using anti-static mats and wristbands and not damaging anything, still I was prepared for nothing to happen when I turned it on, and luckily it woke up and got to a warning saying CPU fan error.
Once I remembered that wasn't an issue I went into the BIOS and noticed only 8GB of RAM were being noticed. Cue another slight panic, until I notice 2 of the sticks are not in fully. Restarting it properly and turning the warning off for the CPU fan in the BIOS everything is working.
Some more pictures (using photobucket now so hopefully will be better) showing the final rig with the fluid running through the system. All comments greatly appreciated along with suggestions to make it better/notice any stupid mistakes I have made. Also, still in need for a name, So suggestions please!
Last thing, thanks to everyone on this forum (Overclock3d as a whole) as most of the information for this build was gathered whilst snooping round this site and to TTL for the videos.