The card is the same, so I think he'll get 3Gb. The card underpowers itself only when it's crossfired with a different GPU, the GPU here is the same, so yeah. I'm not sure though.
the card does not share it memory with other cards
the card will utilise as much memory from it's own resources when it is used
most of us know that... with two cards installed (sli/CFx)(without overclocking), they will always run at the slowest cards' speed.
this means that if the slowest card has the most memory there will be less chance of bottlenecking when processing HLSL/FX stuff.
but, if the reverse is true (fastest card has more memory).. the weaker card will be a PITA, as it will just slow the GPU computations down on BOTH cards