Found out that my PC is 'Fake Booting' -
http://en.wikipedia.org/wiki/Fake_boot
Since I turn my PC off at the wall at night it has to do one of these in order to set the BIOS again
Anooother question
How come my system seems to take ages on the Windows boot screen even though it is clocked stable @ 3.6GhZ?
Seems to take bloody ages to boot, but it's fine once it's booted.