Mate SpeedFan is an epic program.
Your PC is running a bit (and by a bit I mean a bit) hot.
The icons in the program (the blue arrow, the tick, the fire sign) are set at default at what it thinks is good and bad.
Do not worry about the GPU, as mine is currently residing at 53 C on idle and the only reason your is probably hotter is because thee might not be enough ventilation.
Now for your CPU, I would recommend you get a better air cooler if you are using your stock cooler. If you are using a custom cooler then I would probably recommend better thermal paste.
But for now could you answer the following questions:
Is the air from the GPU being released outside of the case or is it still trapped inside the case?
Also, what kind of air cooler do you have? To find out, look at the top of the fan somewhere in the centre there should be a brand. Check your CPU
Oh and that second fan on the motherboard is too cool your Northbridge.
PS: Welcome to the forums.